I published a new version of my experimental Chrome Dark Mode Toggle extension.
On top of a per-origin override, you can now set a Chrome-wide preference to have your OS in Dark Mode but all sites in Light Mode (or vice versa).
Sites can also request an override, thanks to the Web Preferences API.
See https://brm.us/chrome-dark-mode-toggle for more details.
If you would like to have this UA-wide dark/light mode preference (that is independent of the system setting) built into Chrome itself, go give https://issues.chromium.org/issues/40116544 an upvote by hitting the star icon in the top right corner.